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10.1113/jphysiol.2013.255687 J Physiol

doi: 10.1111/j.1399-3054.1990.tb04396.x

Compared to cytosolic NADK (cNADK), mitochondrial NADK (mNADK) has a distinctive feature that it can directly phosphorylate nicotinamide adenine dinucleotide (NADH) to generate NADPH to alleviate oxidative stress in mitochondria

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The importance of Cys and SAM availability for these metabolic adjustments was emphasized by the observation of a cystathionine switch, as demonstrated in egtA 26933

It is a tripeptide with a gamma peptide linkage between the carboxyl group of the glutamate side-chain and the amine group of cysteine, and the carboxyl group of cysteine is attached by a normal peptide linkage to a glycine